Monday, 7 December 2015

How Much White Out Do You Use?





Let's start with a little game to get us thinking about titanium dioxide. From the list of uses below, put them in the correct category. If you think titanium dioxide will be found in the product say yes, and if not put it in the no category.

paints, gasoline, light bulbs, plastics, toothpaste, coloring of foods, sunscreen, diamonds, clothing, ceramics, white out (2)

YES                                                                       NO
                                                                         paint                                                                   gasoline
                                                                       plastics                                                                lightbulbs 
                                                                    toothpaste                                                             diamonds
                                                                         foods
                                                                     sunscreen
                                                                       clothing
                                                                     white out 
                                                                      ceramics

Answer: Use your cursor to highlight the text

How'd you do? Those aren't the only places you will find titanium dioxide. It can also be found in rubber boots, tires, and mascara (2). You may be wondering how this random chemical you have never heard of before ended up in all these things! Well, titanium dioxide is highly reflective and is easily dispersed (4). These two qualities sound like the perfect combination for white paint. You want to be able to spread it easily and we know sun rays reflect off of white. Titanium dioxide is also insoluble, non-flammable, thermally stable, AND the best part is, it's cheap! (3, 4)

If it's so wonderful then why does everyone have their knickers in a knot about it? It is believed that its production as nanoparticles (very, very, very, very small particles), are bad for our health. But the good news is, we aren't being exposed to enough of it for it to be a problem (1). Only in very high concentrations does it have the potential to make us sick (1).

Now I bet you are wondering how it is made (as all good scientists do). If you were to head deep down into a mine, you would be able to find the dirty version of the stuff (4). We need it to be "clean" so we can use it. We can do that in two ways.
            1. Sulfate process - mixing our titanium dioxide sludge with sulfuric acid (4)
            2. Chloride process - mixing the sludge with chlorine gas and petroleum coke (which looks similar to coal) (4)

Since we haven't had any problems with using titanium dioxide so far, we haven't had to think of any backups in case we run out. But if we did, we could use rice starch (3) to whiten foods or diatomaceous earth to whiten paint (5).


So next time you are out and about, try and see how many things you can find that contain titanium dioxide. I bet you will be surprised!







References

1. Australian Government Department of Health. (2015). Nano titanium dioxide technical information sheet. Retrieved December 3, 2015 from http://www.nicnas.gov.au/communications/ issues/nanomaterials-nanotechnology/nicnas-technical-activities-in-nanomaterials/nano-titanium-dioxide-human-health-hazard-review/nano-titanium-dioxide-technical-information-sheet
2. Hext, P. M., Tomenson, J. A., & Thompson, P. (2005). Titanium dioxide: Inhalation toxicology and epidemiology. Annals of Occupational Hygiene, 49(6), 461-472. Doi:10.1093/annhyg/ mei012
3. Industry Sourcing. (2014). Rice starch as an alternative to titanium dioxide. Retrieved December 3, 2015 from http://www.industrysourcing.com/article/rice-starch-alternative-titanium-dioxide
4. Lakshmanan, V. I., Bhowmick, A., & Halim, M. A. (2014). Titanium dioxide: Production, properties, and applications. Chemical Physics Research Journal, 7(1), 37-91. 
5. Specifier. (2011). Alternatives to titanium dioxide for paint industry. Retrieved December 3, 2015 from http://www.specifile.co.za/specifier/coatings-insulation-and-waterproofing/799-alternatives-to-titanium-dioxide-for-paint-industry

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